diff --git a/LehrerApp.Core/AiPlanning/AiPlanningDtos.cs b/LehrerApp.Core/AiPlanning/AiPlanningDtos.cs
index fade0f8..aa1227d 100644
--- a/LehrerApp.Core/AiPlanning/AiPlanningDtos.cs
+++ b/LehrerApp.Core/AiPlanning/AiPlanningDtos.cs
@@ -153,3 +153,24 @@ public class AiHazardSubstance
     public string HStatements { get; set; } = "";
     public string PStatements { get; set; } = "";
 }
+
+/// <summary>
+/// Wire-Vertrag für die Chemikalien-Recherche (ai-backend/substance.php, Nutzerwunsch neben 4.2):
+/// ein reiner Datenbank-Lookup gegen die lokale RiSU-Stoffliste, kein KI-Aufruf (siehe
+/// ai-backend/stoffliste.php) — der Name "Ai..." bleibt trotzdem bestehen, da der Aufruf über
+/// dieselbe Anmeldung/denselben Host wie die echten KI-Endpunkte läuft. Eigener, sehr schmaler
+/// Wire-Vertrag statt Wiederverwendung von AiHazardSubstance — die Recherche liefert
+/// zusätzliche, nur hier relevante Felder (CAS, Signalwort, Tätigkeitsbeschränkung, Quelle).
+/// Enthält bewusst KEIN Entsorgungsfeld — die RiSU-Stoffliste führt keine Entsorgungshinweise.
+/// </summary>
+public class AiSubstanceResearchResponse
+{
+    public string Name { get; set; } = "";
+    public string Cas { get; set; } = "";
+    public List<string> GhsPictograms { get; set; } = [];
+    public string SignalWord { get; set; } = "";
+    public string HStatements { get; set; } = "";
+    public string PStatements { get; set; } = "";
+    public string ActivityRestriction { get; set; } = "";
+    public string Source { get; set; } = "";
+}
diff --git a/LehrerApp.Core/Models/HazardAssessment.cs b/LehrerApp.Core/Models/HazardAssessment.cs
index 985d67a..6a81662 100644
--- a/LehrerApp.Core/Models/HazardAssessment.cs
+++ b/LehrerApp.Core/Models/HazardAssessment.cs
@@ -31,15 +31,25 @@ public class HazardAssessment
 public class HazardSubstance
 {
     public string Name { get; set; } = "";
+    /// CAS-Nummer, falls über die Chemikalien-Recherche (TODO.md 4.2-Nachtrag) ermittelt oder von
+    /// Hand eingetragen — optional, nur zur eindeutigeren Wiedererkennung/Recherche.
+    public string Cas { get; set; } = "";
     /// Typische Einsatzmenge, z.B. "ca. 2 g" — Freitext statt strukturierter Einheit, da der
     /// Rahmen (fest/Lösung/Gas, Konzentration ...) zu unterschiedlich für ein starres Feld ist.
     public string Amount { get; set; } = "";
     public List<GhsPictogram> GhsPictograms { get; set; } = [];
+    /// "Gefahr" oder "Achtung" (GHS-Signalwort) — Freitext statt Enum, da GESTIS-Recherchen auch
+    /// mal ohne eindeutiges Signalwort zurückkommen können.
+    public string SignalWord { get; set; } = "";
     /// H-Sätze (Gefahrenhinweise) als Freitext, z.B. "H314, H290" oder mit Kurztext — bewusst kein
     /// eingebauter Katalog amtlicher H-/P-Satz-Texte in der App (Fehlerrisiko bei
     /// sicherheitsrelevanten Angaben), die Lehrkraft prüft/ergänzt gegen das Sicherheitsdatenblatt.
     public string HStatements { get; set; } = "";
     public string PStatements { get; set; } = "";
+    /// Tätigkeitsbeschränkung laut RiSU-Stoffliste (Freigabe für alle/Schulversuche/nur
+    /// Lehrkraft, Altersgrenzen, Ersatzstoffprüfung nötig, verboten, ...) — Freitext, da die
+    /// tatsächlichen Formulierungen zu unterschiedlich für ein starres Feld/Enum sind.
+    public string ActivityRestriction { get; set; } = "";
 }
 
 public enum ExperimentKind { Lehrerversuch, Schuelerversuch, Demonstrationsversuch }
diff --git a/LehrerApp.Desktop.Tests/HazardAssessmentWizardViewModelTests.cs b/LehrerApp.Desktop.Tests/HazardAssessmentWizardViewModelTests.cs
index afb1515..72b7ae6 100644
--- a/LehrerApp.Desktop.Tests/HazardAssessmentWizardViewModelTests.cs
+++ b/LehrerApp.Desktop.Tests/HazardAssessmentWizardViewModelTests.cs
@@ -1,4 +1,6 @@
+using LehrerApp.Core.AiPlanning;
 using LehrerApp.Core.Models;
+using LehrerApp.Desktop.Services;
 using LehrerApp.Desktop.ViewModels.Groups;
 using Xunit;
 
@@ -8,6 +10,13 @@ public sealed class HazardAssessmentWizardViewModelTests
 {
     private static HazardAssessmentWizardViewModel Build(HazardAssessment? editing = null) => new(editing, "10c");
 
+    private static string BuildTempPath()
+    {
+        var path = Path.Combine(Path.GetTempPath(), $"lehrerapp-gbuwizard-tests-{Guid.NewGuid():N}");
+        Directory.CreateDirectory(path);
+        return path;
+    }
+
     [Fact]
     public void Neu_StartetAufSchritt0OhneKiOhneEditingKennzeichnung()
     {
@@ -227,6 +236,111 @@ public sealed class HazardAssessmentWizardViewModelTests
         Assert.Equal("Notiz", vm.Notes);
         Assert.True(vm.IsAiAssisted);
     }
+
+    [Fact]
+    public void CanUseAi_OhneKiAbhaengigkeiten_IstFalseUndSubstanzenKoennenNichtRecherchieren()
+    {
+        var vm = Build();
+        vm.AddSubstanceCommand.Execute(null);
+
+        Assert.False(vm.CanUseAi);
+        Assert.False(vm.Substances[0].CanResearch);
+    }
+
+    [Fact]
+    public void CanUseAi_MitAngemeldeterKiUndUnitUndLesson_IstTrueUndSubstanzenKoennenRecherchieren()
+    {
+        var aiSettings = new AiSettingsService(BuildTempPath());
+        aiSettings.SetEnabled(true);
+        aiSettings.SetCredentialsAndToken("sebastian", "token-abc");
+        var ai = new AiPlanningService(new HttpClient(), new FakeLessons(), new FakeGroups([]),
+            new FakeSubjects([]), new FakeCompetencyDomains(), new FakeAlternativeLessonPaths([]));
+        var unit = new Unit { Title = "Redoxreaktionen" };
+        var lesson = new Lesson { Topic = "Natrium in Wasser" };
+
+        var vm = new HazardAssessmentWizardViewModel(null, "10c", ai, aiSettings, unit, lesson);
+        vm.AddSubstanceCommand.Execute(null);
+
+        Assert.True(vm.CanUseAi);
+        Assert.True(vm.Substances[0].CanResearch);
+    }
+}
+
+public sealed class HazardSubstanceEditItemTests
+{
+    [Fact]
+    public async Task Research_OhneOnResearch_TutNichtsUndBleibtOhneFehler()
+    {
+        var item = new HazardSubstanceEditItem { Name = "Natrium" };
+
+        await item.ResearchCommand.ExecuteAsync(null);
+
+        Assert.Equal("", item.ResearchError);
+        Assert.False(item.IsResearching);
+    }
+
+    [Fact]
+    public async Task Research_OhneNamen_SetztFehlerUndRuftDelegateNicht()
+    {
+        var called = false;
+        var item = new HazardSubstanceEditItem
+        {
+            Name = "  ",
+            OnResearch = _ => { called = true; return Task.FromResult(new AiSubstanceResearchResponse()); },
+        };
+
+        await item.ResearchCommand.ExecuteAsync(null);
+
+        Assert.False(called);
+        Assert.Equal("Stoffname eingeben.", item.ResearchError);
+    }
+
+    [Fact]
+    public async Task Research_UebernimmtAlleFelderAusDerAntwort()
+    {
+        var item = new HazardSubstanceEditItem { Name = "Natrium" };
+        item.OnResearch = name =>
+        {
+            Assert.Equal("Natrium", name);
+            return Task.FromResult(new AiSubstanceResearchResponse
+            {
+                Name = "Natrium",
+                Cas = "7440-23-5",
+                SignalWord = "Gefahr",
+                HStatements = "H260",
+                PStatements = "P223, P231+P232",
+                ActivityRestriction = "Für Schüler ab der 5. Klasse freigegeben",
+                GhsPictograms = ["GHS02", "GHS05"],
+            });
+        };
+
+        await item.ResearchCommand.ExecuteAsync(null);
+
+        Assert.Equal("Natrium", item.Name);
+        Assert.Equal("7440-23-5", item.Cas);
+        Assert.Equal("Gefahr", item.SignalWord);
+        Assert.Equal("H260", item.HStatements);
+        Assert.Equal("P223, P231+P232", item.PStatements);
+        Assert.Equal("Für Schüler ab der 5. Klasse freigegeben", item.ActivityRestriction);
+        Assert.True(item.PictogramOptions.Single(o => o.Value == GhsPictogram.Flammable).IsSelected);
+        Assert.True(item.PictogramOptions.Single(o => o.Value == GhsPictogram.Corrosive).IsSelected);
+        Assert.False(item.PictogramOptions.Single(o => o.Value == GhsPictogram.Toxic).IsSelected);
+        Assert.False(item.IsResearching);
+        Assert.Equal("", item.ResearchError);
+    }
+
+    [Fact]
+    public async Task Research_BeiFehler_SetztResearchErrorUndBehaeltAlteFelderUnveraendert()
+    {
+        var item = new HazardSubstanceEditItem { Name = "Unbekannt", HStatements = "H999" };
+        item.OnResearch = _ => throw new AiBackendException("Nicht genügend KI-Guthaben. Bitte Guthaben aufladen.");
+
+        await item.ResearchCommand.ExecuteAsync(null);
+
+        Assert.Equal("Nicht genügend KI-Guthaben. Bitte Guthaben aufladen.", item.ResearchError);
+        Assert.Equal("H999", item.HStatements);
+        Assert.False(item.IsResearching);
+    }
 }
 
 public sealed class ExperimentKindDisplayTests
diff --git a/LehrerApp.Desktop.Tests/PdfExportServiceTests.cs b/LehrerApp.Desktop.Tests/PdfExportServiceTests.cs
index e860fb5..fc7bdca 100644
--- a/LehrerApp.Desktop.Tests/PdfExportServiceTests.cs
+++ b/LehrerApp.Desktop.Tests/PdfExportServiceTests.cs
@@ -162,8 +162,9 @@ public sealed class PdfExportServiceTests
             "Natrium in Wasser", "10c", "12.09.2026", "Lehrerversuch",
             "Ein kleines Stück Natrium wird in eine Schale mit Wasser gegeben.",
             [
-                new HazardSubstancePrintRow("Natrium", "ca. 0,5 g", "GHS02, GHS05",
-                    "H260 - Reagiert mit Wasser unter Bildung entzündbarer Gase", "P223, P231+P232, P370+P378"),
+                new HazardSubstancePrintRow("Natrium", "7440-23-5", "ca. 0,5 g", "GHS02, GHS05", "Gefahr",
+                    "H260 - Reagiert mit Wasser unter Bildung entzündbarer Gase", "P223, P231+P232, P370+P378",
+                    "Abgabe an unter 18-Jährige verboten"),
             ],
             ["Wasserstoffbildung, Verpuffungsgefahr", "Verätzungsgefahr durch Natronlauge"],
             ["Schutzbrille", "Sicherheitsabstand einhalten", "Abzug/Freiluftversuch"],
diff --git a/LehrerApp.Desktop/Services/AiPlanningService.cs b/LehrerApp.Desktop/Services/AiPlanningService.cs
index abb331b..1b58ce3 100644
--- a/LehrerApp.Desktop/Services/AiPlanningService.cs
+++ b/LehrerApp.Desktop/Services/AiPlanningService.cs
@@ -76,6 +76,29 @@ public class AiPlanningService(HttpClient http, ILessonRepository lessons,
         Converters = { new GermanDateOnlyJsonConverter(), new GermanTimeOnlyJsonConverter() },
     };
 
+    /// <summary>
+    /// Baut eine nutzergerichtete Fehlermeldung für eine fehlgeschlagene Backend-Antwort, die
+    /// weder 401 noch 402 war (die haben eigene, feste Meldungen). Liest den vom Backend
+    /// gesendeten Klartext-Grund (<c>ai_backend_fail</c> liefert immer <c>{"error": "..."}</c>)
+    /// mit, statt nur eine pauschale Meldung zu zeigen — ohne das war z.B. beim Fehlschlagen der
+    /// Websuche in substance.php (falscher Tool-Bezeichner, fehlender Beta-Header o.ä.) der
+    /// eigentliche Grund nirgends sichtbar, nur "Die Anfrage ist fehlgeschlagen".
+    /// </summary>
+    private static async Task<AiBackendException> BuildRequestFailedExceptionAsync(HttpResponseMessage resp)
+    {
+        string? backendReason = null;
+        try
+        {
+            var body = await resp.Content.ReadFromJsonAsync<BackendErrorResult>(JsonOptions);
+            backendReason = string.IsNullOrWhiteSpace(body?.Error) ? null : body!.Error;
+        }
+        catch { /* Antwortkörper war kein valides {"error": "..."}-JSON - Fallback unten greift. */ }
+
+        return new AiBackendException(backendReason is null
+            ? "Die Anfrage an den KI-Dienst ist fehlgeschlagen."
+            : $"Die Anfrage an den KI-Dienst ist fehlgeschlagen: {backendReason}");
+    }
+
     public async Task<string> LoginAsync(string username, string password)
     {
         HttpResponseMessage resp;
@@ -327,7 +350,7 @@ public class AiPlanningService(HttpClient http, ILessonRepository lessons,
         if (resp.StatusCode == (HttpStatusCode)402)
             throw new AiBackendException("Nicht genügend KI-Guthaben. Bitte Guthaben aufladen.");
         if (!resp.IsSuccessStatusCode)
-            throw new AiBackendException("Die Anfrage an den KI-Dienst ist fehlgeschlagen.");
+            throw await BuildRequestFailedExceptionAsync(resp);
 
         try
         {
@@ -368,7 +391,7 @@ public class AiPlanningService(HttpClient http, ILessonRepository lessons,
         if (resp.StatusCode == (HttpStatusCode)402)
             throw new AiBackendException("Nicht genügend KI-Guthaben. Bitte Guthaben aufladen.");
         if (!resp.IsSuccessStatusCode)
-            throw new AiBackendException("Die Anfrage an den KI-Dienst ist fehlgeschlagen.");
+            throw await BuildRequestFailedExceptionAsync(resp);
 
         try
         {
@@ -409,7 +432,7 @@ public class AiPlanningService(HttpClient http, ILessonRepository lessons,
         if (resp.StatusCode == (HttpStatusCode)402)
             throw new AiBackendException("Nicht genügend KI-Guthaben. Bitte Guthaben aufladen.");
         if (!resp.IsSuccessStatusCode)
-            throw new AiBackendException("Die Anfrage an den KI-Dienst ist fehlgeschlagen.");
+            throw await BuildRequestFailedExceptionAsync(resp);
 
         try
         {
@@ -422,6 +445,46 @@ public class AiPlanningService(HttpClient http, ILessonRepository lessons,
         }
     }
 
+    /// <summary>
+    /// Fragt sicherheitsrelevante Daten zu einer Chemikalie ab (Nutzerwunsch neben 4.2): eigener
+    /// Endpunkt <c>ai-backend/substance.php</c>, serverseitig dateibasiert gecacht (Name/CAS,
+    /// Ablauffrist je nach Einstufung) — wiederholte Anfragen für denselben Stoff verursachen
+    /// nach dem ersten Mal keine weiteren Kosten mehr. Kein Unit-/Guppen-Kontext nötig, nur der
+    /// eingetippte Stoffname.
+    /// </summary>
+    public async Task<AiSubstanceResearchResponse> RequestSubstanceResearchAsync(string substanceName, string token)
+    {
+        using var req = new HttpRequestMessage(HttpMethod.Post, "substance.php")
+        {
+            Content = JsonContent.Create(new { name = substanceName }, options: JsonOptions),
+        };
+        req.Headers.Authorization = new("Bearer", token);
+
+        HttpResponseMessage resp;
+        try { resp = await http.SendAsync(req); }
+        catch (HttpRequestException)
+        {
+            throw new AiBackendException("Der KI-Dienst ist nicht erreichbar. Bitte Internetverbindung prüfen.");
+        }
+
+        if (resp.StatusCode == HttpStatusCode.Unauthorized)
+            throw new AiBackendException("Anmeldung abgelaufen. Bitte in den Einstellungen erneut anmelden.");
+        if (resp.StatusCode == (HttpStatusCode)402)
+            throw new AiBackendException("Nicht genügend KI-Guthaben. Bitte Guthaben aufladen.");
+        if (!resp.IsSuccessStatusCode)
+            throw await BuildRequestFailedExceptionAsync(resp);
+
+        try
+        {
+            var result = await resp.Content.ReadFromJsonAsync<AiSubstanceResearchResponse>(JsonOptions);
+            return result ?? throw new AiBackendException("Die Antwort der KI konnte nicht verarbeitet werden.");
+        }
+        catch (Exception ex) when (ex is not AiBackendException)
+        {
+            throw new AiBackendException("Die Antwort der KI konnte nicht verarbeitet werden. Bitte erneut versuchen.");
+        }
+    }
+
     /// <summary>
     /// Rein (nur Repository-Lesezugriff für den Alternativpfad-Katalog, kein Schreiben) — testbar
     /// mit Fakes. Gibt die zu speichernden Lesson-Objekte zurück; der Aufrufer ruft
@@ -478,4 +541,5 @@ public class AiPlanningService(HttpClient http, ILessonRepository lessons,
 
     private class LoginResult { public string Token { get; set; } = ""; }
     private class BalanceResult { public decimal BalanceUsd { get; set; } }
+    private class BackendErrorResult { public string? Error { get; set; } }
 }
diff --git a/LehrerApp.Desktop/Services/PdfExportService.cs b/LehrerApp.Desktop/Services/PdfExportService.cs
index 81e6ce0..e271b33 100644
--- a/LehrerApp.Desktop/Services/PdfExportService.cs
+++ b/LehrerApp.Desktop/Services/PdfExportService.cs
@@ -88,7 +88,8 @@ public sealed record HazardAssessmentPrintData(
     bool IsAiAssisted);
 
 public sealed record HazardSubstancePrintRow(
-    string Name, string Amount, string Pictograms, string HStatements, string PStatements);
+    string Name, string Cas, string Amount, string Pictograms, string SignalWord,
+    string HStatements, string PStatements, string ActivityRestriction);
 
 /// <summary>
 /// PDF-Erzeugung über QuestPDF (11.3). Liefert fertige Bytes - der Speicherdialog läuft wie bei
@@ -380,7 +381,7 @@ public sealed class PdfExportService
                 if (!string.IsNullOrWhiteSpace(data.Procedure))
                     column.Item().Element(c => TextSection(c, "Durchführung", data.Procedure));
                 if (data.Substances.Count > 0)
-                    column.Item().Element(c => SubstanceTable(c, data.Substances));
+                    column.Item().Element(c => SubstanceBlocks(c, data.Substances));
                 if (data.Hazards.Count > 0)
                     column.Item().Element(c => BulletSection(c, "Gefährdungen", data.Hazards));
                 if (data.ProtectiveMeasures.Count > 0)
@@ -419,37 +420,43 @@ public sealed class PdfExportService
                 column.Item().Text($"• {item}");
         });
 
-    private static void SubstanceTable(IContainer container, IReadOnlyList<HazardSubstancePrintRow> rows) =>
+    /// Eigener Block je Gefahrstoff statt einer engen Tabelle — bei sieben Datenpunkten pro Stoff
+    /// (inkl. CAS, Signalwort, Altersbeschränkung) wäre eine Tabelle auf A4-Hochformat zu schmal
+    /// für lesbare H-/P-Satz-Texte.
+    private static void SubstanceBlocks(IContainer container, IReadOnlyList<HazardSubstancePrintRow> rows) =>
         container.Column(column =>
         {
+            column.Spacing(6);
             column.Item().Text("Gefahrstoffe").FontSize(11).SemiBold();
-            column.Item().Table(table =>
+            foreach (var row in rows)
+                column.Item().Element(c => SubstanceBlock(c, row));
+        });
+
+    private static void SubstanceBlock(IContainer container, HazardSubstancePrintRow row) =>
+        container.Border(0.8f).BorderColor(Colors.Grey.Lighten2).Padding(6).Column(block =>
+        {
+            block.Spacing(2);
+            block.Item().Row(header =>
             {
-                table.ColumnsDefinition(columns =>
+                header.RelativeItem().Text(text =>
                 {
-                    columns.RelativeColumn(2f);
-                    columns.RelativeColumn(1f);
-                    columns.RelativeColumn(1.3f);
-                    columns.RelativeColumn(2f);
-                    columns.RelativeColumn(2f);
+                    text.Span(row.Name).SemiBold();
+                    if (!string.IsNullOrWhiteSpace(row.Cas)) text.Span($"  ·  CAS {row.Cas}").FontColor(Colors.Grey.Darken1);
+                    if (!string.IsNullOrWhiteSpace(row.Amount)) text.Span($"  ·  {row.Amount}").FontColor(Colors.Grey.Darken1);
                 });
-                table.Header(header =>
-                {
-                    header.Cell().Element(HeaderCell).Text("Stoff").SemiBold();
-                    header.Cell().Element(HeaderCell).Text("Menge").SemiBold();
-                    header.Cell().Element(HeaderCell).Text("GHS").SemiBold();
-                    header.Cell().Element(HeaderCell).Text("H-Sätze").SemiBold();
-                    header.Cell().Element(HeaderCell).Text("P-Sätze").SemiBold();
-                });
-                foreach (var row in rows)
-                {
-                    table.Cell().Element(BodyCell).Text(row.Name);
-                    table.Cell().Element(BodyCell).Text(row.Amount);
-                    table.Cell().Element(BodyCell).Text(row.Pictograms);
-                    table.Cell().Element(BodyCell).Text(row.HStatements);
-                    table.Cell().Element(BodyCell).Text(row.PStatements);
-                }
+                if (!string.IsNullOrWhiteSpace(row.SignalWord))
+                    header.ConstantItem(70).AlignRight().Text(row.SignalWord).SemiBold()
+                        .FontColor(Colors.Red.Darken2);
             });
+            if (!string.IsNullOrWhiteSpace(row.Pictograms))
+                block.Item().Text($"GHS: {row.Pictograms}").FontSize(8).FontColor(Colors.Grey.Darken1);
+            if (!string.IsNullOrWhiteSpace(row.HStatements))
+                block.Item().Text($"H-Sätze: {row.HStatements}");
+            if (!string.IsNullOrWhiteSpace(row.PStatements))
+                block.Item().Text($"P-Sätze: {row.PStatements}");
+            if (!string.IsNullOrWhiteSpace(row.ActivityRestriction))
+                block.Item().Text($"Tätigkeitsbeschränkung: {row.ActivityRestriction}").SemiBold()
+                    .FontColor(Colors.Orange.Darken3);
         });
 
     /// <summary>Horizontaler Balken, 0-100 % der verfügbaren Zellenbreite (max. 150pt).</summary>
diff --git a/LehrerApp.Desktop/ViewModels/Groups/HazardAssessmentWizardViewModel.cs b/LehrerApp.Desktop/ViewModels/Groups/HazardAssessmentWizardViewModel.cs
index b00c11b..6b83c59 100644
--- a/LehrerApp.Desktop/ViewModels/Groups/HazardAssessmentWizardViewModel.cs
+++ b/LehrerApp.Desktop/ViewModels/Groups/HazardAssessmentWizardViewModel.cs
@@ -80,32 +80,81 @@ public partial class GhsPictogramOption(GhsPictogram value, string label) : Obse
 public partial class HazardSubstanceEditItem : ObservableObject
 {
     [ObservableProperty] private string _name = "";
+    [ObservableProperty] private string _cas = "";
     [ObservableProperty] private string _amount = "";
+    [ObservableProperty] private string _signalWord = "";
     [ObservableProperty] private string _hStatements = "";
     [ObservableProperty] private string _pStatements = "";
+    [ObservableProperty] private string _activityRestriction = "";
+    [ObservableProperty] private bool _isResearching;
+    [ObservableProperty] private string _researchError = "";
     public ObservableCollection<GhsPictogramOption> PictogramOptions { get; }
     public Action<HazardSubstanceEditItem>? OnRemove { get; set; }
 
+    /// Vom Wizard gesetzt (nur wenn eine KI-Backend-Anmeldung vorliegt, siehe CanUseAi — der
+    /// Lookup selbst ruft aber keine KI auf, sondern nur die lokale RiSU-Stoffliste auf dem
+    /// Server, siehe ai-backend/substance.php): führt die eigentliche Chemikalien-Recherche aus.
+    /// Wird vor der Anzeige in der UI (Objektinitialisierer in NewSubstanceItem) endgültig
+    /// gesetzt, daher genügt eine einmalig berechnete Eigenschaft ohne Änderungsbenachrichtigung.
+    public Func<string, Task<AiSubstanceResearchResponse>>? OnResearch { get; set; }
+    public bool CanResearch => OnResearch is not null;
+
     public HazardSubstanceEditItem(HazardSubstance? source = null)
     {
         PictogramOptions = new ObservableCollection<GhsPictogramOption>(
             GhsPictogramDisplay.BuildOptions(source?.GhsPictograms));
         if (source is null) return;
         Name = source.Name;
+        Cas = source.Cas;
         Amount = source.Amount;
+        SignalWord = source.SignalWord;
         HStatements = source.HStatements;
         PStatements = source.PStatements;
+        ActivityRestriction = source.ActivityRestriction;
     }
 
     [RelayCommand]
     private void Remove() => OnRemove?.Invoke(this);
 
+    [RelayCommand]
+    private async Task Research()
+    {
+        if (OnResearch is null) return;
+        if (string.IsNullOrWhiteSpace(Name)) { ResearchError = "Stoffname eingeben."; return; }
+
+        ResearchError = ""; IsResearching = true;
+        try
+        {
+            var result = await OnResearch(Name.Trim());
+            Name = result.Name;
+            Cas = result.Cas;
+            SignalWord = result.SignalWord;
+            HStatements = result.HStatements;
+            PStatements = result.PStatements;
+            ActivityRestriction = result.ActivityRestriction;
+            var pictograms = result.GhsPictograms
+                .Select(GhsPictogramDisplay.FromCode).Where(p => p.HasValue).Select(p => p!.Value).ToHashSet();
+            foreach (var option in PictogramOptions) option.IsSelected = pictograms.Contains(option.Value);
+        }
+        catch (AiBackendException ex)
+        {
+            ResearchError = ex.Message;
+        }
+        finally
+        {
+            IsResearching = false;
+        }
+    }
+
     public HazardSubstance ToModel() => new()
     {
         Name = Name.Trim(),
+        Cas = Cas.Trim(),
         Amount = Amount.Trim(),
+        SignalWord = SignalWord.Trim(),
         HStatements = HStatements.Trim(),
         PStatements = PStatements.Trim(),
+        ActivityRestriction = ActivityRestriction.Trim(),
         GhsPictograms = PictogramOptions.Where(o => o.IsSelected).Select(o => o.Value).ToList(),
     };
 }
@@ -217,10 +266,25 @@ public partial class HazardAssessmentWizardViewModel : ObservableObject
 
     private HazardSubstanceEditItem NewSubstanceItem(HazardSubstance? source = null)
     {
-        var item = new HazardSubstanceEditItem(source) { OnRemove = RemoveSubstance };
+        var item = new HazardSubstanceEditItem(source)
+        {
+            OnRemove = RemoveSubstance,
+            OnResearch = CanUseAi ? ResearchSubstanceAsync : null,
+        };
         return item;
     }
 
+    /// Führt die eigentliche Chemikalien-Recherche aus — ein reiner Datenbank-Lookup gegen die
+    /// lokale RiSU-Stoffliste auf dem Server (ai-backend/stoffliste.php), keine KI beteiligt und
+    /// damit auch kein IsAiAssisted-Hinweis nötig. Die Anmeldung läuft trotzdem über dieselbe
+    /// KI-Backend-Sitzung wie die echten KI-Funktionen (gemeinsamer Host/Token).
+    private async Task<AiSubstanceResearchResponse> ResearchSubstanceAsync(string substanceName)
+    {
+        var token = _aiSettings!.GetToken()
+            ?? throw new AiBackendException("Nicht angemeldet. Bitte in den Einstellungen bei der KI-Unterstützung anmelden.");
+        return await _ai!.RequestSubstanceResearchAsync(substanceName, token);
+    }
+
     [RelayCommand]
     private void AddSubstance() => Substances.Add(NewSubstanceItem());
 
diff --git a/LehrerApp.Desktop/Views/Groups/HazardAssessmentWizardDialog.axaml b/LehrerApp.Desktop/Views/Groups/HazardAssessmentWizardDialog.axaml
index d36742f..e5cb1d8 100644
--- a/LehrerApp.Desktop/Views/Groups/HazardAssessmentWizardDialog.axaml
+++ b/LehrerApp.Desktop/Views/Groups/HazardAssessmentWizardDialog.axaml
@@ -81,14 +81,32 @@
                 <Border BorderBrush="{DynamicResource SystemControlForegroundBaseLowBrush}"
                         BorderThickness="0,0,0,1" Padding="0,10">
                   <StackPanel Spacing="6">
-                    <Grid ColumnDefinitions="*,140,Auto">
+                    <Grid ColumnDefinitions="*,Auto,Auto">
                       <TextBox Grid.Column="0" Text="{Binding Name}" PlaceholderText="Stoffname"
                                 Margin="0,0,8,0"/>
-                      <TextBox Grid.Column="1" Text="{Binding Amount}" PlaceholderText="Menge, z.B. ca. 2 g"
-                                Margin="0,0,8,0"/>
+                      <Button Grid.Column="1" Content="🔍 Recherchieren" Command="{Binding ResearchCommand}"
+                              IsVisible="{Binding CanResearch}" IsEnabled="{Binding !IsResearching}"
+                              Margin="0,0,8,0"
+                              ToolTip.Tip="Sucht Piktogramme, Signalwort, H-/P-Sätze und Tätigkeitsbeschränkung in der RiSU-Stoffliste (Sicheres Experimentieren im Unterricht)."/>
                       <Button Grid.Column="2" Content="✕" Command="{Binding RemoveCommand}"
                               ToolTip.Tip="Stoff entfernen"/>
                     </Grid>
+                    <TextBlock Text="{Binding ResearchError}" Foreground="Red" FontSize="11"
+                               IsVisible="{Binding ResearchError, Converter={x:Static StringConverters.IsNotNullOrEmpty}}"/>
+                    <Grid ColumnDefinitions="*,12,140,12,140">
+                      <StackPanel Grid.Column="0" Spacing="2">
+                        <TextBlock Text="CAS-Nummer" FontSize="11" Opacity="0.6"/>
+                        <TextBox Text="{Binding Cas}" PlaceholderText="z.B. 7440-23-5"/>
+                      </StackPanel>
+                      <StackPanel Grid.Column="2" Spacing="2">
+                        <TextBlock Text="Menge" FontSize="11" Opacity="0.6"/>
+                        <TextBox Text="{Binding Amount}" PlaceholderText="z.B. ca. 2 g"/>
+                      </StackPanel>
+                      <StackPanel Grid.Column="4" Spacing="2">
+                        <TextBlock Text="Signalwort" FontSize="11" Opacity="0.6"/>
+                        <TextBox Text="{Binding SignalWord}" PlaceholderText="Gefahr/Achtung"/>
+                      </StackPanel>
+                    </Grid>
                     <ItemsControl ItemsSource="{Binding PictogramOptions}">
                       <ItemsControl.ItemsPanel>
                         <ItemsPanelTemplate><WrapPanel ItemSpacing="10" LineSpacing="4"/></ItemsPanelTemplate>
@@ -109,6 +127,11 @@
                         <TextBox Text="{Binding PStatements}" PlaceholderText="z.B. P280, P305+P351+P338"/>
                       </StackPanel>
                     </Grid>
+                    <StackPanel Spacing="2">
+                      <TextBlock Text="Tätigkeitsbeschränkung" FontSize="11" Opacity="0.6"/>
+                      <TextBox Text="{Binding ActivityRestriction}"
+                                PlaceholderText="z.B. Für Schüler ab der 5. Klasse freigegeben"/>
+                    </StackPanel>
                   </StackPanel>
                 </Border>
               </DataTemplate>
diff --git a/LehrerApp.Desktop/Views/Groups/LessonDialog.axaml.cs b/LehrerApp.Desktop/Views/Groups/LessonDialog.axaml.cs
index d3660a4..ddc9829 100644
--- a/LehrerApp.Desktop/Views/Groups/LessonDialog.axaml.cs
+++ b/LehrerApp.Desktop/Views/Groups/LessonDialog.axaml.cs
@@ -126,8 +126,8 @@ public partial class LessonDialog : Window
             assessment.Title, assessment.GroupLabel, assessment.Date?.ToString("dd.MM.yyyy") ?? "",
             ExperimentKindDisplay.Label(assessment.Kind), assessment.Procedure,
             assessment.Substances.Select(s => new HazardSubstancePrintRow(
-                s.Name, s.Amount, string.Join(", ", s.GhsPictograms.Select(GhsPictogramDisplay.Code)),
-                s.HStatements, s.PStatements)).ToList(),
+                s.Name, s.Cas, s.Amount, string.Join(", ", s.GhsPictograms.Select(GhsPictogramDisplay.Code)),
+                s.SignalWord, s.HStatements, s.PStatements, s.ActivityRestriction)).ToList(),
             assessment.Hazards, assessment.ProtectiveMeasures, assessment.FirstAid, assessment.Disposal,
             assessment.Notes, assessment.IsAiAssisted);
         var pdf = App.Services.GetRequiredService<PdfExportService>().BuildHazardAssessmentPdf(data);
diff --git a/TODO.md b/TODO.md
index 8f1b96f..24c6063 100644
--- a/TODO.md
+++ b/TODO.md
@@ -595,6 +595,103 @@ Bearbeiten, `ExperimentKindDisplay`/`GhsPictogramDisplay`), zwei neue Fälle in
 wie bei `RequestExplanationAsync`/`RequestPlanAsync` nicht Teil der automatisierten Tests (braucht
 einen echten Endpunkt, siehe Kommentar in `AiPlanningServiceTests.cs`).
 
+**Nachtrag — Chemikalien-Recherche (Nutzerwunsch):** pro Gefahrstoff-Zeile im Wizard ein Button
+"🔍 Recherchieren", der Piktogramme, Signalwort, H-/P-Sätze, CAS-Nummer und Tätigkeitsbeschränkung
+befüllt — `HazardSubstance` bekommt dafür drei neue Felder (`Cas`, `SignalWord`,
+`ActivityRestriction`).
+
+**Weg dorthin (drei verworfene Zwischenstände, der Reihe nach):**
+1. Zuerst versucht: KI mit Anthropics Websuche-Tool, auf die GESTIS-Domain eingeschränkt.
+   Scheiterte durchgängig ("nicht sicher auffindbar"), auch für zweifelsfrei in GESTIS erfasste
+   Stoffe.
+2. Ursachenanalyse ergab: `gestis.dguv.de` ist eine reine JavaScript-Anwendung ohne
+   serverseitig gerenderten Inhalt (nur ein leeres `<div id="app">`) — weder eine Websuche noch
+   ein einfacher HTTP-Abruf konnte dort je etwas finden, unabhängig von einer bekannten URL. Über
+   das öffentlich ausgelieferte JS-Bundle der Seite wurde GESTIS' eigene (inoffizielle)
+   Daten-API gefunden und direkt verifiziert (inkl. des ebenfalls öffentlich in
+   `gestis.dguv.de/env-config.js` ausgelieferten Zugangsschlüssels) — technisch funktionierte der
+   Direktabruf, aber GESTIS selbst hat keine strukturierte, schulspezifische
+   Tätigkeitsbeschränkung hinterlegt (nur eine allgemeine Jugendarbeitsschutzgesetz-Floskel plus
+   Verweis auf eine externe, nicht abrufbare Publikation) — genau die für den Unterricht
+   wichtigste Angabe fehlte also weiterhin.
+3. Der Nutzer stellte stattdessen die offizielle **RiSU-Stoffliste** ("Richtlinie Sicheres
+   Experimentieren im Unterricht") als PDF bereit (123 Seiten, wkhtmltopdf-Export einer
+   Datenbanktabelle) — enthält Name, CAS-Nr., ZVG-Nr., GHS-Piktogramme, Signalwort, H-/P-Sätze
+   UND eine eigene Tätigkeitsbeschränkungs-Spalte (Freigabe/Verbot/Altersgrenzen/
+   Ersatzstoffprüfung/Lehrkraft-Vorbehalt) — exakt das gesuchte Datenmodell, gezielt für den
+   Schuleinsatz zusammengestellt statt eines allgemeinen Arbeitsschutz-Nachschlagewerks.
+
+**Endgültige Architektur — reiner lokaler Datenbank-Lookup, keine KI mehr beteiligt**
+(Nutzervorgabe: "wir brauchen die KI gar nicht mehr im Backend. Es reicht die reine Datenbank."):
+- Das 123-seitige PDF wurde einmalig (per `pdfplumber`, Tabellen-Extraktion je Seite, robuste
+  CAS-Nummer-Rekonstruktion über zeilenweise wrappende Bindestrich-Enden) in
+  [data/stoffliste.json](../ai-backend/data/stoffliste.json) umgewandelt (~1800 Stoffe, ~760 KB).
+- Neuer Endpunkt [substance.php](../ai-backend/substance.php): prüft weiterhin das Bearer-Token
+  (`ai_backend_authenticate`), sucht den angefragten Namen aber nur noch exakt (normalisiert,
+  auch gegen CAS-Nummer/verwandte CAS-Nummern) in [stoffliste.php](../ai-backend/stoffliste.php)
+  — bewusst **kein** Fuzzy-/Teilstring-Match, ein falscher Treffer wäre hier schlimmer als gar
+  keiner. Kein KI-Aufruf, keine Kosten, keine Drittanbieter-Netzwerkabhängigkeit mehr; ohne
+  Treffer liefert der Endpunkt einen klaren 404 statt eines Rateversuchs.
+- Die gesamte für dieses Feature eingeführte Tool-Use-/Websuche-Infrastruktur wurde vollständig
+  zurückgebaut, da nicht mehr gebraucht: `ProviderInterface`/`AnthropicProvider`/`FakeProvider`/
+  `ai_backend_call_and_charge` wieder auf ihren ursprünglichen (Vor-Feature-)Stand, `gestis.php`,
+  `cache.php`, `data/gestis-substances.json` und die Migration für
+  `transactions.web_search_requests` wieder entfernt.
+- **Legende der Tätigkeitsbeschränkungs-Codes** (steht in keiner Form im PDF selbst; die erste
+  vom Nutzer erinnerte Fassung war falsch und wurde nach einem zweiten Blick korrigiert — u.a.
+  `S`/`L+` bedeuten das genaue GEGENTEIL der ersten Fassung, ein Verbot statt einer Freigabe):
+  `+` generelle Erlaubnis · `X` generelles Tätigkeitsverbot an Schulen · `L+` Tätigkeitsverbot für
+  Lehrkräfte (Ausnahme siehe RiSU I–3.5) · `S` Tätigkeitsverbot für Schüler:innen · `S4K`
+  Tätigkeitsverbot bis einschließlich Jahrgangsstufe 4 · `S9K` bis einschließlich Jahrgangsstufe 9
+  · `W` Tätigkeitsverbot für werdende/stillende Mütter · `ESP` gesonderte Ersatzstoffprüfung
+  notwendig (unverändert). Aus diesem Anlass Architektur angepasst: `data/stoffliste.json`
+  speichert nur noch die rohen Codes, die Übersetzung passiert erst zur Abfragezeit in
+  `stoffliste.php` (`STOFFLISTE_RESTRICTION_LEGEND`) — eine künftige Korrektur braucht damit nur
+  noch eine Codeänderung statt einer kompletten Neu-Generierung der ~1800-Stoffe-Datenbank.
+- **Datenqualität:** beim Regenerieren der Datenbank für obige Korrektur zusätzlich eine
+  Kopfzeilen-Dublette gefunden und behoben (Erkennung war zu strikt auf unverzerrten Text
+  angewiesen) sowie entdeckt, dass `pdfplumber`s Tabellenerkennung bei ca. 40 der ca. 1800 Stoffe
+  (~2 %) die Spalten nicht sauber trennen konnte (ungewöhnlich lange Zellinhalte lassen die
+  Spaltenerkennung für einzelne Zeilen kollabieren). Für diese Zeilen wurde eine Regex-basierte
+  Rekonstruktion versucht (CAS-/GHS-/H-/P-Code-Muster sind positionsunabhängig eindeutig,
+  Stoffname dagegen nicht) — nur bei einem eindeutig plausiblen Stoffnamen übernommen (11 von 51
+  gerettet), der Rest bewusst ausgelassen statt mit einem möglicherweise falschen Namen
+  aufgenommen zu werden (ein falscher Name bei sonst korrekten Gefahrendaten wäre gefährlicher als
+  ein fehlender Eintrag). Endgültige Größe: 1764 Stoffe.
+- **Bekannte Lücke:** diese Stoffliste enthält keine Entsorgungshinweise (anders als der
+  verworfene GESTIS-Ansatz) — `Disposal` bleibt bei einem Datenbank-Treffer leer und muss
+  weiterhin von Hand ausgefüllt werden.
+- Deployment: `substance.php`, `stoffliste.php` und `data/stoffliste.json` hochladen — kein
+  Migrations-Schritt, keine `config.php`-Änderung mehr nötig (siehe `ai-backend/README.md`).
+
+**Feld umbenannt:** `HazardSubstance.AgeRestriction` → `ActivityRestriction` (Wizard-Feld
+"Umgangsbeschränkung für Schüler (nach Alter)" → "Tätigkeitsbeschränkung"), da die tatsächlich
+verfügbare Angabe breiter ist als reine Altersgrenzen (Freigabe/Verbot/Ersatzstoffprüfung/
+Lehrkraft-Vorbehalt gehören genauso dazu) — der ursprüngliche Feldname war eine zum Zeitpunkt der
+ersten Umsetzung noch zu enge Annahme.
+
+**Auf dem Weg dorthin außerdem behoben (nicht mehr relevant für die Endarchitektur, aber
+allgemein nützlich):** der Desktop-Client zeigte bei jedem Backend-Fehler ≠ 401/402 nur die
+pauschale Meldung "Die Anfrage an den KI-Dienst ist fehlgeschlagen" statt der von
+`ai_backend_fail` tatsächlich mitgesendeten Ursache (`{"error": "..."}`) — betraf alle KI-Aufrufe
+(`RequestPlanAsync`/`RequestExplanationAsync`/`RequestHazardAssessmentDraftAsync`), nicht nur die
+Chemikalien-Recherche. Neue gemeinsame `AiPlanningService.BuildRequestFailedExceptionAsync` liest
+das `error`-Feld mit und hängt es an die Meldung an — bleibt auch nach diesem Umbau nützlich.
+
+**PDF-Export:** Gefahrstoffe werden jetzt als eigener Block je Stoff statt als schmale
+Tabellenzeile gedruckt (`PdfExportService.SubstanceBlocks`/`SubstanceBlock`) — bei den vielen
+Datenpunkten je Stoff (Name, CAS, Menge, GHS, Signalwort, H-/P-Sätze, Tätigkeitsbeschränkung) wäre
+eine Tabelle auf A4-Hochformat zu schmal für lesbare Texte geworden; die Tätigkeitsbeschränkung
+wird farblich hervorgehoben, da sie die operativ wichtigste Angabe für die Lehrkraft ist.
+
+Neue Tests: `HazardSubstanceEditItemTests` (Delegate-Aufruf, Feldübernahme, Fehlerbehandlung,
+leerer Name), zwei neue `CanUseAi`/`CanResearch`-Wiring-Tests in
+`HazardAssessmentWizardViewModelTests`. Die eigentliche HTTP-Anfrage von
+`RequestSubstanceResearchAsync` ist nicht Teil der automatisierten Tests (kein PHP im
+Implementierungsumfeld verfügbar); die PDF→JSON-Umwandlung und die Lookup-Logik wurden in Python
+nachgebaut und gegen reale Stichproben aus dem PDF verifiziert. Für `ai-backend/` selbst existiert
+weiterhin keine automatisierte Testsuite (kein PHP-Testframework im Projekt).
+
 ### 4.3 Stundenplan
 - [x] **4.3.1** Neues Modell `TimetableSlot` (Gruppe, Wochentag, Stunde, Raum) + Repository —
       [Planning.cs](LehrerApp.Core/Models/Planning.cs),
diff --git a/ai-backend/README.md b/ai-backend/README.md
index 7090750..2ed3c80 100644
--- a/ai-backend/README.md
+++ b/ai-backend/README.md
@@ -84,6 +84,61 @@ in `db.php` verschoben, damit `explain.php` sie mitverwenden kann, ohne sie zu d
 Kein neues DB-Schema nötig (nutzt dieselben `users`/`tokens`/`transactions`-Tabellen wie
 `plan.php`/`explain.php`). Einfach die neue Datei `gbu.php` hochladen.
 
+## Update für bereits deployte Installationen (Chemikalien-Recherche, `substance.php`)
+
+Neues Feature — reiner lokaler Datenbank-Lookup, **kein KI-Aufruf, keine Kosten, keine
+Drittanbieter-Abhängigkeit** (Nutzerwunsch: "wir brauchen die KI gar nicht mehr im Backend").
+
+Vorgeschichte in Kurzform (Details siehe TODO.md, Nachtrag zu 4.2): zunächst wurde versucht, die
+Daten per KI-Websuche bei GESTIS zu recherchieren — das scheiterte, weil `gestis.dguv.de` eine
+reine JavaScript-Anwendung ohne durchsuchbaren/abrufbaren Inhalt ist. Ein direkter Abruf über
+GESTIS' eigene (inoffizielle) API funktionierte zwar technisch, hatte aber keine strukturierte,
+schulspezifische Tätigkeitsbeschränkung (Freigabe/Verbot/Altersgrenzen) — genau die für den
+Unterricht wichtigste Angabe. Der Nutzer stellte stattdessen die offizielle **RiSU-Stoffliste**
+("Richtlinie Sicheres Experimentieren im Unterricht") als PDF bereit — ein für den Schuleinsatz
+zusammengestelltes Verzeichnis mit exakt den benötigten Spalten (Name, CAS-Nr., GHS-Piktogramme,
+Signalwort, H-/P-Sätze UND Tätigkeitsbeschränkung), aus dem `data/stoffliste.json` (~1800 Stoffe)
+erzeugt wurde. `substance.php` ist damit auf einen reinen, kostenlosen Datenbank-Lookup reduziert.
+
+**Deployment:** neue Dateien `substance.php` und `stoffliste.php` hochladen, sowie
+`data/stoffliste.json` (~760 KB, nur lesend benötigt). Kein Migrations-Schritt, keine
+`config.php`-Änderung nötig — der Endpunkt prüft weiterhin das Bearer-Token wie jeder andere
+(`ai_backend_authenticate`), braucht aber keinerlei KI-/Abrechnungs-Infrastruktur mehr.
+
+**Legende der Tätigkeitsbeschränkungs-Codes** (steht in keiner Form im PDF selbst, vom Nutzer
+bestätigt — Übersetzung passiert zur Abfragezeit in `stoffliste.php`
+(`STOFFLISTE_RESTRICTION_LEGEND`), bewusst NICHT in `data/stoffliste.json` gespeichert, damit eine
+künftige Korrektur nur eine Codeänderung statt einer neuen Datenbank-Generierung braucht — genau
+das war hier schon einmal nötig, die erste Fassung dieser Legende war falsch):
+
+| Code | Bedeutung |
+| --- | --- |
+| `+` | Generelle Erlaubnis |
+| `X` | Generelles Tätigkeitsverbot an Schulen |
+| `L+` | Tätigkeitsverbot für Lehrkräfte, Ausnahme siehe RiSU (I – 3.5) |
+| `S` | Tätigkeitsverbot für Schülerinnen und Schüler |
+| `S4K` | Tätigkeitsverbot für Schülerinnen und Schüler bis einschließlich Jahrgangsstufe 4 |
+| `S9K` | Tätigkeitsverbot für Schülerinnen und Schüler bis einschließlich Jahrgangsstufe 9 |
+| `W` | Tätigkeitsverbot für werdende oder stillende Mütter |
+| `ESP` | Gesonderte Ersatzstoffprüfung notwendig |
+
+**Bekannte Lücken:**
+- Diese Stoffliste enthält keine Entsorgungshinweise (anders als der frühere GESTIS-Ansatz) — das
+  `disposal`-Feld im Wizard bleibt bei einem Datenbank-Treffer leer und muss weiterhin von Hand
+  ausgefüllt werden.
+- Für ca. 40 der ca. 1800 Stoffe im PDF (~2 %) konnte die Tabellenerkennung die Spalten nicht
+  zuverlässig auseinanderhalten (ungewöhnlich lange Zellinhalte lassen `pdfplumber`s
+  Spaltenerkennung für einzelne Zeilen kollabieren) — betroffene Zeilen wurden NICHT mit
+  geratenen/möglicherweise falschen Werten aufgenommen, sondern bewusst ausgelassen (ein falscher
+  Stoffname bei sonst korrekten Gefahrendaten wäre gefährlicher als ein fehlender Eintrag). Bei
+  Bedarf lässt sich die Liste der fehlenden Stoffe aus dem PDF neu ermitteln.
+
+**Aktualisieren der Datenbank:** wenn die RiSU-Stoffliste künftig überarbeitet wird, das PDF neu
+herunterladen und `data/stoffliste.json` neu erzeugen (Parsing-Logik ist nicht Teil des Repos,
+da einmalig genutzt — bei Bedarf erneut über `pdfplumber` extrahieren, Spaltenreihenfolge siehe
+`stoffliste.php`-Kommentar). Die Tätigkeitsbeschränkungs-**Codes** werden weiterhin mit
+gespeichert, nur ihre Übersetzung lebt separat in `STOFFLISTE_RESTRICTION_LEGEND`.
+
 ## Prompt Caching
 
 Der Systemprompt in `plan.php` ist vollständig statisch (identisch bei jeder Anfrage, jedes
@@ -143,6 +198,21 @@ grundsätzlich nicht) — dann hilft nur eine serverseitige Konfiguration durch
 - Ob Prompt Caching tatsächlich greift (`cache_read_input_tokens` > 0 bei einer zweiten Anfrage
   innerhalb von 5 Minuten) — der `FakeProvider` simuliert kein Caching, das lässt sich nur gegen
   die echte Anthropic-API beobachten (z.B. per Blick in die `transactions`-Tabelle).
+- **`substance.php`/`stoffliste.php` (Chemikalien-Recherche):** braucht keinen echten API-Key und
+  keine Netzwerkverbindung mehr, ist also grundsätzlich einfacher zu verifizieren als der Rest
+  dieser Liste — trotzdem NICHT in einer echten PHP-Umgebung gelaufen (kein PHP auf der
+  Implementierungs-Maschine verfügbar). Die Lookup-/Normalisierungslogik in `stoffliste.php` sowie
+  der PDF→JSON-Umwandlungsschritt für `data/stoffliste.json` wurden in Python nachgebaut und
+  gegen Stichproben verifiziert (u.a. Natrium, Kaliumdichromat, Zinn-Verbindungen), nicht aber der
+  tatsächlich ausgeführte PHP-Code selbst — vor dem produktiven Einsatz einmal mit ein paar
+  bekannten Stoffnamen durchtesten.
+  **Nachtrag (Nutzer-Testlauf):** eine harte `allowed_domains`-Einschränkung auf GESTIS lieferte
+  für tatsächlich vorhandene Stoffe trotzdem "nicht sicher auffindbar" — vermutlich liefert die
+  Websuche für GESTIS' dynamisch aufgebaute Seiten zu wenige brauchbar indexierte Treffer.
+  `allowed_domains` wurde daraufhin entfernt; die Quellenrangfolge (GESTIS zuerst, sonst andere
+  anerkannte Quellen) steht jetzt nur noch im Systemprompt, mit Pflichtangabe der tatsächlich
+  genutzten Quelle im `source`-Feld. Ob GESTIS damit in der Praxis öfter tatsächlich als Quelle
+  gefunden wird, ist weiterhin nur mit echten Testläufen zu beurteilen.
 
 ## Guthaben aufladen
 
diff --git a/ai-backend/data/stoffliste.json b/ai-backend/data/stoffliste.json
new file mode 100644
index 0000000..28cb3d5
--- /dev/null
+++ b/ai-backend/data/stoffliste.json
@@ -0,0 +1 @@
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schädigen","Gewässergefährdend","Gesundheits​schädlich"],"activityRestrictionCodes":["S4K","ESP"]},{"name":"Zinn(II)-oxid","cas":"21651-19-4","relatedCas":[],"zvg":"133090","signalWord":"","ghsPictograms":[],"hStatements":[],"pStatements":[],"hazardCategories":[],"activityRestrictionCodes":["+"]},{"name":"Zinn(II)-sulfat","cas":"7488-55-3","relatedCas":[],"zvg":"5500","signalWord":"Gefahr","ghsPictograms":["GHS05","GHS07","GHS08"],"hStatements":["H315","H317","H318","H332","H335","H373","H412"],"pStatements":["P280","P310","P302+P352","P304+P340","P332+P313","P305+P351+P338"],"hazardCategories":["Reizend","Allergisierend bei Hautkontakt","Ätzend/Korrosiv","Gesundheits​schädlich","Kann die Organe schädigen","Gewässergefährdend"],"activityRestrictionCodes":["S4K","ESP"]},{"name":"Zinn(IV)-chlorid","cas":"7646-78-8","relatedCas":[],"zvg":"3590","signalWord":"Gefahr","ghsPictograms":["GHS05","GHS07"],"hStatements":["H314","H335","H412"],"pStatements":["P261","P271","P273","P280","P303+P361+P353","P305+P351+P338"],"hazardCategories":["Ätzend/Korrosiv","Reizend","Gewässergefährdend"],"activityRestrictionCodes":["S4K","ESP"]},{"name":"Zinn(IV)-oxid","cas":"18282-10-5","relatedCas":[],"zvg":"3860","signalWord":"","ghsPictograms":[],"hStatements":[],"pStatements":[],"hazardCategories":[],"activityRestrictionCodes":["+"]},{"name":"Zirkonium, Pulver, nicht stabilisiert","cas":"7440-67-7","relatedCas":[],"zvg":"7400","signalWord":"Gefahr","ghsPictograms":["GHS02"],"hStatements":["H250","H260"],"pStatements":["P222","P223","P422","P231+P232","P370+P378"],"hazardCategories":["Selbstentzündlich","Reagiert heftig mit Wasser"],"activityRestrictionCodes":["S4K"]},{"name":"Zirkonium(IV)-oxid","cas":"1314-23-4","relatedCas":[],"zvg":"4000","signalWord":"","ghsPictograms":[],"hStatements":[],"pStatements":[],"hazardCategories":[],"activityRestrictionCodes":["+"]},{"name":"Zirkonylchlorid Zirconiumdichloridoxid","cas":"7699-43-6","relatedCas":["15461-27-5","13520-92-8"],"zvg":"3290","signalWord":"Gefahr","ghsPictograms":["GHS05"],"hStatements":["H314"],"pStatements":["P280","P310","P305+P351+P338"],"hazardCategories":["Ätzend/Korrosiv"],"activityRestrictionCodes":["S4K"]},{"name":"Zitronenöl","cas":"84929-31-7","relatedCas":[],"zvg":"237","signalWord":"Gefahr","ghsPictograms":["GHS02","GHS07","GHS08","GHS09"],"hStatements":["H226","H304","H315","H317","H410"],"pStatements":["P101","P331","P501","P301+P310","P302+P352","P333+P313"],"hazardCategories":["Entzündbar","Aspirations​gefahr lebensgefährlich","Reizend","Allergisierend bei Hautkontakt","Gewässergefährdend"],"activityRestrictionCodes":["S4K"]},{"name":"Zitronensäure 20% 2-Hydroxypropan-1,2,3-tricarbonsäure w=20%","cas":"","relatedCas":[],"zvg":"35230.002","signalWord":"Achtung","ghsPictograms":["GHS07"],"hStatements":["H319","H335"],"pStatements":["P280","P337+P313","P305+P351+P338"],"hazardCategories":["Reizend"],"activityRestrictionCodes":["S4K"]},{"name":"Zitronensäure 5% 2-Hydroxypropan-1,2,3-tricarbonsäure w=5%","cas":"","relatedCas":[],"zvg":"35230.003","signalWord":"","ghsPictograms":[],"hStatements":[],"pStatements":[],"hazardCategories":[],"activityRestrictionCodes":["+"]},{"name":"Zitronensäure-1-Hydrat 2-Hydroxypropan-1,2,3-tricarbonsäure-Monohydrat","cas":"5949-29-1","relatedCas":[],"zvg":"35230","signalWord":"Achtung","ghsPictograms":["GHS07"],"hStatements":["H319","H335"],"pStatements":["P261","P264","P271","P280","P304+P340+P312","P305+P351+P338"],"hazardCategories":["Reizend"],"activityRestrictionCodes":["S4K"]}]
\ No newline at end of file
diff --git a/ai-backend/stoffliste.php b/ai-backend/stoffliste.php
new file mode 100644
index 0000000..c4a81b7
--- /dev/null
+++ b/ai-backend/stoffliste.php
@@ -0,0 +1,101 @@
+<?php
+declare(strict_types=1);
+
+/**
+ * Lokale Datenbank aus der RiSU-Stoffliste ("Richtlinie Sicheres Experimentieren im Unterricht"),
+ * vom Nutzer als offizielles PDF bereitgestellt (stoffliste.pdf, 123 Seiten, ~1800 Stoffe) und
+ * einmalig in data/stoffliste.json umgewandelt. Ersetzt die vorher versuchten GESTIS-/KI-Websuche-
+ * Ansätze vollständig (siehe TODO.md-Nachtrag zu 4.2): GESTIS selbst hatte weder zuverlässig
+ * abrufbare noch schulspezifische Tätigkeitsbeschränkungs-Angaben, diese Stoffliste ist dagegen
+ * gezielt für den Schuleinsatz zusammengestellt und enthält die Tätigkeitsbeschränkung (Freigabe/
+ * Verbot/Altersgrenzen/Ersatzstoffprüfung/Lehrkraft-Vorbehalt) direkt als eigene Spalte — die
+ * eigentlich entscheidende Angabe für eine schulische Gefährdungsbeurteilung.
+ *
+ * Reiner lokaler Datenbank-Lookup, kein KI-Aufruf mehr nötig (Nutzerwunsch: "wir brauchen die KI
+ * gar nicht mehr im Backend. Es reicht die reine Datenbank.").
+ *
+ * data/stoffliste.json speichert bewusst nur die rohen Tätigkeitsbeschränkungs-CODES, nicht die
+ * übersetzten Texte — die Übersetzung passiert erst hier, zur Abfragezeit (siehe
+ * STOFFLISTE_RESTRICTION_LEGEND). So reicht bei einer künftigen Korrektur der Legende (wie schon
+ * einmal nötig — die erste Fassung war falsch) eine Änderung an einer einzigen Stelle, statt die
+ * komplette ~1800 Stoffe umfassende Datenbank neu erzeugen zu müssen.
+ */
+
+const STOFFLISTE_PATH = __DIR__ . '/data/stoffliste.json';
+
+/** Vom Nutzer bestätigte Legende (steht in keiner Form im PDF selbst). */
+const STOFFLISTE_RESTRICTION_LEGEND = [
+    '+' => 'Generelle Erlaubnis',
+    'X' => 'Generelles Tätigkeitsverbot an Schulen',
+    'L+' => 'Tätigkeitsverbot für Lehrkräfte, Ausnahme siehe RiSU (I – 3.5)',
+    'S' => 'Tätigkeitsverbot für Schülerinnen und Schüler',
+    'S4K' => 'Tätigkeitsverbot für Schülerinnen und Schüler bis einschließlich Jahrgangsstufe 4',
+    'S9K' => 'Tätigkeitsverbot für Schülerinnen und Schüler bis einschließlich Jahrgangsstufe 9',
+    'W' => 'Tätigkeitsverbot für werdende oder stillende Mütter',
+    'ESP' => 'Gesonderte Ersatzstoffprüfung notwendig',
+];
+
+function stoffliste_normalize(string $value): string
+{
+    return trim(mb_strtolower($value));
+}
+
+/** Übersetzt Tätigkeitsbeschränkungs-Codes in lesbare Texte — unbekannte Codes werden
+ * unverändert durchgereicht (Fail-Open: keinen Hinweis stillschweigend verschwinden lassen,
+ * falls die Liste um einen neuen Code erweitert wird, den diese Legende noch nicht kennt). */
+function stoffliste_restriction_texts(array $codes): array
+{
+    return array_map(
+        fn(string $code) => STOFFLISTE_RESTRICTION_LEGEND[$code] ?? $code,
+        $codes
+    );
+}
+
+/**
+ * @return list<array{
+ *   name: string, cas: string, relatedCas: list<string>, zvg: string, signalWord: string,
+ *   ghsPictograms: list<string>, hStatements: list<string>, pStatements: list<string>,
+ *   hazardCategories: list<string>, activityRestrictionCodes: list<string>
+ * }>
+ */
+function stoffliste_load(): array
+{
+    static $data = null;
+    if ($data !== null) {
+        return $data;
+    }
+    $raw = @file_get_contents(STOFFLISTE_PATH);
+    $decoded = $raw !== false ? json_decode($raw, true) : null;
+    $data = is_array($decoded) ? $decoded : [];
+    return $data;
+}
+
+/**
+ * Sucht einen Stoff exakt (normalisierter Name oder CAS-Nummer, auch gegen "verwandte"
+ * CAS-Nummern bei Stoffen mit mehreren erfassten CAS-Nummern) — bewusst kein Fuzzy-/Teilstring-
+ * Match, ein falscher Treffer wäre hier schlimmer als gar keiner (die Antwort bezöge sich sonst
+ * unbemerkt auf einen falschen Stoff samt dessen Tätigkeitsbeschränkung). Gibt null zurück, wenn
+ * der Stoff nicht in der Liste steht.
+ */
+function stoffliste_lookup(string $query): ?array
+{
+    $normalizedQuery = stoffliste_normalize($query);
+    $data = stoffliste_load();
+
+    foreach ($data as $entry) {
+        if (stoffliste_normalize((string) $entry['name']) === $normalizedQuery) {
+            return $entry;
+        }
+    }
+    foreach ($data as $entry) {
+        if ($entry['cas'] !== '' && stoffliste_normalize((string) $entry['cas']) === $normalizedQuery) {
+            return $entry;
+        }
+        foreach (($entry['relatedCas'] ?? []) as $related) {
+            if (stoffliste_normalize((string) $related) === $normalizedQuery) {
+                return $entry;
+            }
+        }
+    }
+    return null;
+}
diff --git a/ai-backend/substance.php b/ai-backend/substance.php
new file mode 100644
index 0000000..cbc4688
--- /dev/null
+++ b/ai-backend/substance.php
@@ -0,0 +1,37 @@
+<?php
+declare(strict_types=1);
+
+require_once __DIR__ . '/db.php';
+require_once __DIR__ . '/stoffliste.php';
+
+header('Content-Type: application/json');
+
+$config = require __DIR__ . '/config.php';
+$pdo = ai_backend_db($config);
+ai_backend_authenticate($pdo); // nur eingeloggte Nutzer der App dürfen abfragen
+
+$body = json_decode(file_get_contents('php://input'), true);
+if (!is_array($body) || !isset($body['name']) || trim((string) $body['name']) === '') {
+    ai_backend_fail(400, 'Ungültige Anfrage: "name" fehlt.');
+}
+$name = trim((string) $body['name']);
+
+// Reiner Datenbank-Lookup (siehe stoffliste.php) — kein KI-Aufruf, keine Kosten, keine
+// Netzwerkabhängigkeit von Drittanbietern. Findet die App den Stoff nicht, trägt die Lehrkraft
+// die Angaben von Hand ein (kein Rateversuch über eine externe Quelle mehr, siehe TODO.md).
+$entry = stoffliste_lookup($name);
+if ($entry === null) {
+    ai_backend_fail(404, 'Stoff nicht in der RiSU-Stoffliste gefunden. Bitte Schreibweise/CAS-Nummer prüfen oder Angaben manuell eintragen.');
+}
+
+echo json_encode([
+    'name' => $entry['name'],
+    'cas' => $entry['cas'],
+    'ghsPictograms' => $entry['ghsPictograms'],
+    'signalWord' => $entry['signalWord'],
+    'hStatements' => implode(', ', $entry['hStatements']),
+    'pStatements' => implode(', ', $entry['pStatements']),
+    'activityRestriction' => implode('; ', stoffliste_restriction_texts($entry['activityRestrictionCodes'])),
+    'source' => 'RiSU-Stoffliste (Sicheres Experimentieren im Unterricht)'
+        . ($entry['zvg'] !== '' && $entry['zvg'] !== '-' ? ', ZVG ' . $entry['zvg'] : ''),
+]);